综述了锂离子电池锡基负极材料的研究进展.锡基负极材料可分为氧化物、复合氧化物、合金3类.材料的合成方法不同,结构与性能也不-样,但其储锂机理都为合金机理.电解质溶液在电极表面有SEI膜生成.选择合适的电压循环区间,可以提高材料的循环性能.锡合金则是最有希望进入商业化市场的锡基负极材料,其中锡与锂可逆形成合金,另一不与锂反应的金属作为导电基体与框架,容纳合金以改善循环性能.
作 者： 雷钢铁 苏光耀 高德淑 李朝晖  
作者单位： 湘潭大学化学化工学院, 
刊 名： 电池  ISTIC PKU
英文刊名： BATTERY BIMONTHLY 
年，卷(期)： 2001 31(6) 
分类号： TM912.9 
关键词： 锂离子电池   负极材料   锡基材料  
机标分类号： TB3 TG1 
机标关键词： 锂离子电池锡锡基负极材料材料研究概况materials for锡合金循环性能复合氧化物结构与性能电解质溶液储锂机理合成方法电极表面循环区商业化选择市场框架金属基体 
基金项目： 湖南省教委自然科学基金 
DOI：   参考文献(30条)
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引证文献(9条) 
尹朝丽.赵海雷.郭洪.仇卫华.贾喜娣 碳热还原合成SnSb合金负极材料的电化学性能 [期刊论文] -稀有金属材料与工程2007(08)
梁英.范晶.贾志杰 固相反应法制备Sn-SnO-Zn纳米负极材料 [期刊论文] -电池2007(04)
孙竞晔.王莉.何向明.任建国.蒲薇华.姜长印.万春荣 锂离子二次电池铜锡合金负极研究进展 [期刊论文] -科技导报2006(08)
尹朝丽.赵海雷.郭洪.仇卫华 SnSb复合负极材料的合成和电化学性能 [期刊论文] -电池2006(01)
尹朝丽 二次锂离子电池SnSb合金负极材料的研究 [学位论文] 硕士2006
齐智.吴锋 SnO2超细粉的制备与嵌锂性能 [期刊论文] -电池2005(04)
汪飞.赵铭姝.宋晓平 锂离子电池锡基负极材料的研究进展 [期刊论文] -电池2005(02)
高玲 二次锂离子电池Li<,4>Ti<,5>O<,12>负极材料合成动力学及电化学性能研究 [学位论文] 硕士2005
王丽琼.何琼 锂离子电池电极材料的研究进展 [期刊论文] -曲靖师范学院学报2003(06)

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